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26th International Conference on Advanced Nanotechnology

Moscow, Russia

Takahiro Maruyama

Takahiro Maruyama

Meijo University, Japan

Title: Single-walled carbon nanotube synthesis by alcohol catalytic chemical vapour deposition in high vacuum using platinum-group metal catalysts

Biography

Biography: Takahiro Maruyama

Abstract

For the realization of application of single-walled carbon nanotubes (SWCNTs) to electronics devices, control of chirality and reduction of growth temperature have been significant issues. At present, 3d transition metals, such as Fe, Co and Ni, are widely used as catalysts for SWCNT growth in chemical vapour deposition (CVD). However, due to Ostwald ripening, these catalysts are apt to aggregate at the growth temperature, resulting in enlargement of both diameter and chirality distribution of SWCNTs. We performed SWCNT growth by a gas source-type alcohol catalytic CVD system using platinum-group metal catalysts (Ru, Rh, Pd and Pt). By optimizing the ethanol gas supply using a CVD system in a high vacuum, SWCNTs were grown from these metals between 400 and 700ºC. In particular, SWCNTs were grown from Rh catalysts even below 300ºC. Irrespective of catalyst metals, the diameter and chirality distribution of grown SWCNTs became narrower, as the growth temperature decreased. The diameters of most SWCNTs grown from Pt catalysts were below 1 nm, having a narrow chirality distribution. We demonstrated that the platinum-group metal catalysts are effective for both low temperature growth and narrow chirality distribution. Based on the SWCNT diameter and catalyst particle size, we discuss the growth mechanism of SWCNTs from the platinum-group metal catalysts.